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The example will serve to illustrate application of the principles for construction of orbital interaction diagrams and also to illustrate the wealth of information which may be deduced on the basis of the diagrams. Since we are describing the existing bonding of a molecule, we imagine it to originate from the interaction of fragment orbitals. In this situation, some or all of the orbital overlaps will be large and the principles of strong interactions apply. CONSTRUCTION OF INTERACTION DIAGRAM We begin the construction of the diagrams by deciding on the groups which are interacting. If we were interested in only the p bonds, we would note that the p bond is between a tricoordinated atom (the carbon atom) and a monocoordinated atom (the oxygen atom). However, we will not assume prior bonding between the carbon atom and the oxygen atom. Therefore, we will use a bent dicoordinated atom as one of our groups and a zero-coordinated atom for the other. Refer to Figure 3.21 as the development of the interaction diagram progresses. We must next decide on the placement of the groups relative to each other. Since we are attempting to understand the bonding in the carbonyl group, we will position the dicoordinated C atom and the zero-coordinated O atom in the positions and orientations that they occupy in the nished carbonyl group, using our prior knowledge of the structure of the carbonyl group. We also chose to display

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To use Tkinter, import the Tkinter module. Many programmers import it into the local namespace (from Tkinter import *); this is less explicit, but it does save some typing. This chapter s examples don t import Tkinter into the local namespace, in order to make it obvious when they use Tkinter.

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If necessary, zoom and pan so that you can see all three surfaces. Your drawing should look like Figure 23-4. You now have the top, bottom, and middle shelves of the cabinet.

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1. If you did the exercise on Customizing the Buttons Menu, open Windows Explorer and find ab1.cui. Right-click it and choose Copy. Right-click again and choose Paste. Rename the copy ab3.cui. If you have AutoCAD, also find ab1.mnl and rename it ab3.mnl. If you didn t do that exercise, back up acad.cui or aclt.cui. Then use the method just described to make a copy of acad.cui or aclt.cui, and name it ab3.cui.

SELECT p.id AS product_id, p.name AS product_name, p.doc.extract( /doc/summary/text() ).getStringVal() AS summary FROM product p,prod_cat_joiner pcj WHERE pcj.product_cat_id={@category_id} AND p.id=pcj.product_id

1. If you have ab25-03.dwg open from the previous exercise, use this file. Otherwise, open it from your AutoCAD Bible folder (if you did the exercise) or the Results folder of the CD-ROM. 2. Save the file as ab25-04.dwg in your AutoCAD Bible folder. If the Render toolbar is not open, right-click any toolbar and choose Render. 3. Choose Materials Library from the Render toolbar. Hold down Ctrl, and scroll as necessary to choose Beige Plastic, Green Glass, Light Wood Tile, Pink Marble, Stitched Pattern, White Matte, Wood Med. Ash, Wood White Ash, and Yellow Plastic. Click Import.

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In order to nd its position on the Earth s surface, a GPS receiver needs to nd its distances from at least four satellites. Theoretically, it needs only three, but the clock on the receiver is not accurate enough to allow this. Distance is measured by measuring the time taken for the GPS signal to travel from the satellite to the receiver. As the time taken is only 0.06 second for a satellite immediately overhead, an error of one thousandth of a second would give an error of 200 miles! Each satellite has an onboard Atomic Clock , which is super accurate, but for each receiver to be similarly equipped, GPS would not be a practical proposition. Satellites transmit a semi-random signal, which the receiver matches with its own semi-random signal. The distance the receiver has to move its own signal to get a match is a measure of the time difference and a range can then be calculated. It s a bit like matching continually repeated barcodes in reality. This is accurate enough to get a rst guess at the distance. Fixing Position with GPS If the distance to the satellite is calculated by the receiver, it can be plotted as a position line, where any place on the Earth s surface is the same distance from the satellite. The receiver must lie somewhere on that position line. If the distances from two more satellites are calculated and plotted, the receiver must lie on all three lines. Normally, this can occur at only one point on the Earth s surface and so that must indicate the position of the receiver.

If you view the Plot and Publish Details, you see a report like the one shown in Figure 17-19. You can see details for all plots that you did in the current session of AutoCAD or AutoCAD LT.

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